New PDF release: Advances in Catalysis and Related Subjects, Volume 25

By Daniel Douglas Eley, etc.

ISBN-10: 0120078252

ISBN-13: 9780120078257

Considering the fact that 1948, this serial has sought to fill the space among the papers and the textbooks that train the varied parts of catalysis learn. This quantity contains articles at the functions of adsorption microcalorimetry and natural syntheses utilizing aluminosilicates.

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Additional resources for Advances in Catalysis and Related Subjects, Volume 25

Sample text

The lower-energy orbital is stabilized and the upper-energy orbital is destabilized by the interaction. A general rule (73) regarding the direction of orbital shifting can be learned from Fig. 25. Orbitals of adsorbed atoms are raised or lowered in energy depending on whether the ionization potentials of substrate orbitals are smaller or greater, respectively, than the ionization potentials of orbitals on adsorbed atoms. The extent of orbital shifting is dependent on the magnitude of overlap between interacting orbitals.

3 eV by Hotop and Bennett (42), the clusters have better electron-accepting abilities than the single atom. The electronic properties of silver aggregates change from a semiconductor type at a few atoms toward a metal type at several atoms. , spacing of a few kT between energy levels). Figure 6 shows the energy gap between HOMO and LUMO as a function of aggregate size for linear aggregates. Apparently the ZP and EA are converging t o a value =7 eV. These results indicate a longwavelength shift in light absorption as particle size increases.

BAETZOLD ing energies per atom for adsorbed and isolated Ag clusters shows that the AgBr lattice stabilizes the Ag cluster in most cases. This effect is due t o the electron donation to the lattice. The electron affinities of adsorbed silver clusters, calculated using Eq. (27), are shown in Table XI. These values indicate that electron-trapping ability of Ag and Ag3 is greater than that of AgBr with the reverse true for Ag, and Ag4. With increasing Ag cluster size, EA increases, as expected for isolated Ag clusters and shown in Fig.

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Advances in Catalysis and Related Subjects, Volume 25 by Daniel Douglas Eley, etc.


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