New PDF release: Advanced Materials in Catalysis

By Frank Bolz (Auth.)

ISBN-10: 012147450X

ISBN-13: 9780121474508

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Catal. 24, 250. Raney, M. (1940). Ind. Eng. Chem. 32, 1199. Reynolds, P. W. (1950). J. Chem. Soc. 265. , and Sachtler, W. M. H. (1973). J. Catal. 28, 381. , and Delmon, G. (1973). J. Catal. 30, 333. Sachtler, W. M. , and Dorgelo, G. J. H. (1965). J. Catal. 4, 654. Sampson, R. , and Shooter, D . (1965). In "Oxidation and Combustion Reviews" (C. F. H. ), Vol. I, p. 223. Elsevier, Amsterdam. Sayers, D . , Lytle, F. , and Stern, E. A. (1971). Phys. Rev. Lett. 21, 1204. Schölten, J. , and van Montfoort, A.

J. Catal. 30, 333. Sachtler, W. M. , and Dorgelo, G. J. H. (1965). J. Catal. 4, 654. Sampson, R. , and Shooter, D . (1965). In "Oxidation and Combustion Reviews" (C. F. H. ), Vol. I, p. 223. Elsevier, Amsterdam. Sayers, D . , Lytle, F. , and Stern, E. A. (1971). Phys. Rev. Lett. 21, 1204. Schölten, J. , and van Montfoort, A. (1962). J. Catal. 1, 85. 1 Bimetallic Catalysts 31 Schwab, G. M. (1950). Discuss. Faraday Soc. 8, 166. Seib, D. , and Spicer, W. E. (1970). Phys. Rev. Β 2, 1676. Sinfelt, J.

The spectra of the bimetallic catalysts in Fig. 1 are all characterized by peaks that are broad compared with those for the corresponding bulk alloys. In addition the two peaks for each doublet have unequal linewidths, percent absorptions and areas. This results from a distribution of Fe chemical environments and the vibrational anistropy expected for surface atoms on small clusters (Garten, 1976a). A distribution of Fe environments is expected for small clusters with a high surface-to-volume ratio since the surface atoms occupy a variety of sites corresponding to edges, corners, and faces of the cluster as well as points of contact between these sites and the support.

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Advanced Materials in Catalysis by Frank Bolz (Auth.)


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